Solaris 10 10/08 has the ability to boot with ZFS, I have tested it without any issues but here are some comments from experienced users who have used it for a while
Here is a comment from Reginald Beardsley
My initial install of 10/08 over the top of an old 11/06 system was
unbootable. There was a warning about changing the BIOS boot device,
but doing that had no effect. After I blanked the first 1 MB of the
disk w/ dd, the install worked fine. No BIOS fiddle required.
My initial recommendation would be: Use i in the lab and play with it, don't use it in porduction because is very new, let's wait for another year or two
Best Regards